! reference: ! Marinov, N. M., Pitz, W. J., Westbrook, C. K., Vincitore, A. M., ! Castaldi, M. J., Senkan, S. M. "Aromatic and Polycyclic Aromatic ! Hydrocarbon Formation in a Laminar Premixed n-Butane Flame" ! Combustion and Flame 114 192-213 (1998). ! UCRL-WEB-204236 ! Review and release date: May 19, 2004. ! ! Date: Tue, 19 Jan 1999 11:38:35 -0800 (PST) ! From: "Nick M. Marinov" elements h o c ar n end species h2 h ch4 ch3 ch2 ch ch2o hco co2 co o2 o oh ho2 h2o2 h2o c2h hcco c2h2 c2h3 c2h4 c2h5 c2h6 ch2oh ch3o hccoh h2ccch c3h2 ch2(s) ch2co c4h2 c5h2 c5h3 c6h2 c2 c2o c hcoh ch2chcch hcchcch h2cccch c6h5 c6h6 c6h5o ch2chchch ch2chcch2 h2c4o ch2chchch2 ch3oh ch2hco c-c5h5 c-c5h5o c-c5h6 c6h5oh c10h8 c-c5h4oh c-c5h4o c4h10 pc4h9 sc4h9 c4h8-1 c4h8-2 c4h7 c3h6 ac3h5 pc3h5 sc3h5 ch2chcho pc3h4 ac3h4 ch3co c6h5ch2 c6h5ch3 ch2chco ch3chco ch3hco chocho c3h8 ic3h7 nc3h7 ch3chcch2 ch3ccch2 c6h5c2h5 c10h10 c10h9 c10h7 c6h4c2h3 c6h4c2h c6h5c2h3 c6h5c2h c10h7o c6h5cho c6h5co hoc6h4ch3 c6h5ch2oh oc6h4o oc6h4ch3 c10h7ch2 c10h7ch3 ch3c6h4ch3 indene indenyl acenphthln phnthrn ch3chcch ch3ch2cch ch3c6h4ch2 phnthryl-1 phnthryl-9 flrnthn ch3c6h4c2h3 ch3c6h4c2h5 c-2*4c6h6o c-c5h7 l-c5h8 l-c5h7 c10h7c2h5 c10h7c2h3 c10h7oh c6h5cco c6h5chch c6h5cch2 c10h7cch2 c10h7cch c10h6cch anthracn ch3indene ch3indenyl ch3phnthrn pyrene fluoryl fluorene h2cccch2 chchcho hcccho hccco hc4-p(def)pthn hc4-p(def)pthyl phnthroxy-1 phnthroxy-9 bz(a)ndene bz(a)ndnyl phnthrol-1 phnthrol-9 biphenyl bz(a)phnthrn bz(ghi)fln fulvene ch3cy24pd ch3cy24pd1 ch3dcy24pd cyc6h7 fulvenyl ar n2 end thermo end reactions oh+h2=h+h2o 2.14E+08 1.52 3449.0 !Marinov 1995a o+oh=o2+h 2.02E+14 -0.4 0.0 !Marinov 1995a o+h2=oh+h 5.06E+04 2.67 6290.0 !Marinov 1995a h+o2(+m)=ho2(+m) 4.52E+13 0.0 0.0 !Marinov 1995a low / 1.05E+19 -1.257 0.0 / !Marinov 1995a ! h2o/0.0/ h2/0.0/ ch4/10.0/ co2/3.8/ co/1.9/ h2o/0.0/ h2/0.0/ n2/0.0/ ch4/10.0/ co2/3.8/ co/1.9/ h+o2(+n2)=ho2(+n2) 4.52E+13 0.0 0.0 !Marinov 1995a low / 2.03E+20 -1.59 0.0 / !Marinov 1995a h+o2(+h2)=ho2(+h2) 4.52E+13 0.0 0.0 !Marinov 1995a low / 1.52E+19 -1.133 0.0 / !Marinov 1995a h+o2(+h2o)=ho2(+h2o) 4.52E+13 0.0 0.0 !Marinov 1995a low / 2.10E+23 -2.437 0.0 / !Marinov 1995a oh+ho2=h2o+o2 2.13E+28 -4.827 3500.0 !Hippler 1995 dup oh+ho2=h2o+o2 9.10E+14 0.0 10964.0 !Hippler 1995 dup h+ho2=oh+oh 1.50E+14 0.0 1000.0 !Marinov 1995a h+ho2=h2+o2 8.45E+11 0.65 1241.0 !Marinov 1995a h+ho2=o+h2o 3.01E+13 0.0 1721.0 !Marinov 1995a o+ho2=o2+oh 3.25E+13 0.0 0.0 !Marinov 1995a oh+oh=o+h2o 3.57E+04 2.4 -2112.0 !Marinov 1995a h+h+m=h2+m 1.00E+18 -1.0 0.0 !Marinov 1995a h2o/0.0/ h2/0.0/ h+h+h2=h2+h2 9.20E+16 -0.6 0.0 !Marinov 1995a h+h+h2o=h2+h2o 6.00E+19 -1.25 0.0 !Marinov 1995a h+oh+m=h2o+m 2.21E+22 -2.0 0.0 !Marinov 1995a h2o/6.4/ h+o+m=oh+m 4.71E+18 -1.0 0.0 !Marinov 1995a h2o/6.4/ o+o+m=o2+m 1.89E+13 0.0 -1788.0 !Marinov 1995a ho2+ho2=h2o2+o2 4.20E+14 0.0 11982.0 !Marinov 1995a dup ho2+ho2=h2o2+o2 1.30E+11 0.0 -1629.0 !Marinov 1995a dup oh+oh(+m)=h2o2(+m) 1.24E+14 -0.37 0.0 !Marinov 1995a low / 3.04E+30 -4.63 2049.0 / !Marinov 1995a troe / 0.470 100.0 2000.0 1.0E+15/ h2o2+h=ho2+h2 1.98E+06 2.0 2435.0 !Marinov 1995a h2o2+h=oh+h2o 3.07E+13 0.0 4217.0 !Marinov 1995a h2o2+o=oh+ho2 9.55E+06 2.0 3970.0 !Marinov 1995a h2o2+oh=h2o+ho2 2.40E+00 4.042 -2162.0 !Marinov 1995a ch3+ch3(+m)=c2h6(+m) 9.22E+16 -1.174 636.0 !Walter 1990 low / 1.14E+36 -5.246 1705.0/ !Walter 1990 troe/ 0.405 1120.0 69.6 1.0E+15/ h2o/5.0/ h2/2.0/ co2/3.0/ co/2.0/ ch3+h(+m)=ch4(+m) 2.14E+15 -0.4 0.0 !Tsang 1986 low/ 3.31E+30 -4.0 2108.0 / ! (a) troe / 0.0 1.0E-15 1.0E-15 40.0/ h2o/5.0/ h2/2.0/ co2/3.0/ co/2.0/ ch4+h=ch3+h2 2.20E+04 3.0 8750.0 !Miller 1992 ch4+oh=ch3+h2o 4.19E+06 2.0 2547.0 !Marinov 1995 ch4+o=ch3+oh 6.92E+08 1.56 8485.0 !Marinov 1995 ch4+ho2=ch3+h2o2 1.12E+13 0.0 24640.0 !Marinov 1995 ch3+ho2=ch3o+oh 7.00E+12 0.0 0.0 !Troe 1993 ch3+ho2=ch4+o2 3.00E+12 0.0 0.0 !Marinov 1995 ch3+o=ch2o+h 8.00E+13 0.0 0.0 !Marinov 1995 ch3+o2=ch3o+o 1.45E+13 0.0 29209.0 !Klatt 1991 ch3+o2=ch2o+oh 2.51E+11 0.0 14640.0 !Marinov 1995 ch3o+h=ch3+oh 1.00E+14 0.0 0.0 !Miller 1992 ch3+oh=ch2(s)+h2o 2.65E+13 0.0 2186.0 !Humpfer 1994 ch3+oh=ch2+h2o 3.00E+06 2.0 2500.0 !Marinov 1996 ch3+oh=hcoh+h2 5.48E+13 0.0 2981.0 !Humpfer 1994 ch3+oh=ch2o+h2 2.25E+13 0.0 4300.0 ! (b) ch3+h=ch2+h2 9.00E+13 0.0 15100.0 !Miller 1992 ch3+m=ch+h2+m 6.90E+14 0.0 82469.0 !Markus 1992 ch3+m=ch2+h+m 1.90E+16 0.0 91411.0 !Markus 1992 ch3+oh(+m)=ch3oh(+m) 5.65E+13 0.1 0.0 !Fagerstrom 1993 low/ 5.75E+41 -7.4 626.0 / ! (c) troe / 0.025 1.0E-15 8000.0 3000.0/ h2o /16.0/ h2/2.0/ co2/3.0/ co/2.0/ ch3oh(+m)=hcoh+h2(+m) 4.15E+16 -0.15 92285.0 ! (d) low / 4.23E+44 -7.65 92911.0 / troe / 0.025 1.0E-15 8000.0 3000.0/ h2o/16.0/ h2/2.0/ co2/3.0/ co/2.0/ ch3oh+oh=ch2oh+h2o 2.61E+05 2.182 -1344.0 !Tsang 1987 ch3oh+oh=ch3o+h2o 2.62E+06 2.056 916.0 !Tsang 1987 ch3oh+o=ch2oh+oh 3.88E+05 2.5 3080.0 !Tsang 1987 ch3oh+h=ch2oh+h2 1.70E+07 2.1 4868.0 !Tsang 1987 ch3oh+h=ch3o+h2 4.24E+06 2.1 4868.0 !Tsang 1987 ch3oh+ho2=ch2oh+h2o2 9.64E+10 0.0 12578.0 !Tsang 1987 ch3o+m=ch2o+h+m 5.45E+13 0.0 13497.0 !Choudhury1990 ch2oh+m=ch2o+h+m 1.00E+14 0.0 25000.0 !Miller 1992 ch3o+h=ch2o+h2 2.00E+13 0.0 0.0 !Miller 1992 ch2oh+h=ch2o+h2 2.00E+13 0.0 0.0 !Miller 1992 ch3o+oh=ch2o+h2o 1.00E+13 0.0 0.0 !Miller 1992 ch2oh+oh=ch2o+h2o 1.00E+13 0.0 0.0 !Miller 1992 ch3o+o=ch2o+oh 1.00E+13 0.0 0.0 !Miller 1992 ch2oh+o=ch2o+oh 1.00E+13 0.0 0.0 !Miller 1992 ch3o+o2=ch2o+ho2 6.30E+10 0.0 2600.0 !Miller 1992 ch2oh+o2=ch2o+ho2 1.57E+15 -1.0 0.0 !Baulch 1992 dup ch2oh+o2=ch2o+ho2 7.23E+13 0.0 3577.0 !Baulch 1992 dup hcoh+oh=hco+h2o 2.00E+13 0.0 0.0 !Marinov 1996 hcoh+h=ch2o+h 2.00E+14 0.0 0.0 !Marinov 1996 hcoh+o=co2+h+h 5.00E+13 0.0 0.0 !Marinov 1996 hcoh+o=co+oh+h 3.00E+13 0.0 0.0 !Marinov 1996 hcoh+o2=co2+h+oh 5.00E+12 0.0 0.0 ! (e) hcoh+o2=co2+h2o 3.00E+13 0.0 0.0 ! (e) ch2+h=ch+h2 1.00E+18 -1.56 0.0 !Miller 1992 ch2+oh=ch+h2o 1.13E+07 2.0 3000.0 !Miller 1992 ch2+oh=ch2o+h 2.50E+13 0.0 0.0 !Miller 1992 ch2+co2=ch2o+co 1.10E+11 0.0 1000.0 !Miller 1992 ch2+o=co+h+h 5.00E+13 0.0 0.0 !Miller 1992 ch2+o=co+h2 3.00E+13 0.0 0.0 !Miller 1992 ch2+o2=ch2o+o 3.29E+21 -3.3 2868.0 ! (f) ch2+o2=co2+h+h 3.29E+21 -3.3 2868.0 ! (f) ch2+o2=co2+h2 1.01E+21 -3.3 1508.0 ! (f) ch2+o2=co+h2o 7.28E+19 -2.54 1809.0 ! (f) ch2+o2=hco+oh 1.29E+20 -3.3 284.0 ! (f) ch2+ch3=c2h4+h 4.00E+13 0.0 0.0 ! Miller 1992 ch2+ch2=c2h2+h+h 4.00E+13 0.0 0.0 ! Miller 1992 ch2+hcco=c2h3+co 3.00E+13 0.0 0.0 ! Miller 1992 ch2+c2h2=h2ccch+h 1.20E+13 0.0 6600.0 ! Miller 1992 ch2(s)+m=ch2+m 1.00E+13 0.0 0.0 ! Miller 1992 h /12.0/ c2h2 /4.0/ h2o/3.0/ ch2(s)+ch4=ch3+ch3 4.00E+13 0.0 0.0 ! Miller 1992 ch2(s)+c2h6=ch3+c2h5 1.20E+14 0.0 0.0 ! Miller 1992 ch2(s)+o2=co+oh+h 7.00E+13 0.0 0.0 ! Miller 1992 ch2(s)+h2=ch3+h 7.00E+13 0.0 0.0 ! Miller 1992 ch2(s)+c2h2=h2ccch+h 1.50E+14 0.0 0.0 ! Canosa-Mas85 ch2(s)+c2h4=ac3h5+h 1.30E+14 0.0 0.0 ! Canosa-Mas85 ch2(s)+o=co+h+h 3.00E+13 0.0 0.0 ! Miller 1992 ch2(s)+oh=ch2o+h 3.00E+13 0.0 0.0 ! Miller 1992 ch2(s)+h=ch+h2 3.00E+13 0.0 0.0 ! Miller 1992 ch2(s)+co2=ch2o+co 3.00E+12 0.0 0.0 ! Miller 1992 ch2(s)+ch3=c2h4+h 2.00E+13 0.0 0.0 ! Miller 1992 ch2(s)+ch2co=c2h4+co 1.60E+14 0.0 0.0 ! Miller 1992 ch+o2=hco+o 3.30E+13 0.0 0.0 ! Miller 1992 ch+o=co+h 5.70E+13 0.0 0.0 ! Miller 1992 ch+oh=hco+h 3.00E+13 0.0 0.0 ! Miller 1992 ch+oh=c+h2o 4.00E+07 2.0 3000.0 ! Miller 1992 ch+co2=hco+co 3.40E+12 0.0 690.0 ! Miller 1992 ch+h=c+h2 1.50E+14 0.0 0.0 ! Miller 1992 ch+h2o=ch2o+h 1.17E+15 -0.75 0.0 ! Miller 1992 ch+ch2o=ch2co+h 9.46E+13 0.0 -515.0 ! Miller 1992 ch+c2h2=c3h2+h 1.00E+14 0.0 0.0 ! Miller 1992 ch+ch2=c2h2+h 4.00E+13 0.0 0.0 ! Miller 1992 ch+ch3=c2h3+h 3.00E+13 0.0 0.0 ! Miller 1992 ch+ch4=c2h4+h 6.00E+13 0.0 0.0 ! Miller 1992 c+o2=co+o 2.00E+13 0.0 0.0 ! Miller 1992 c+oh=co+h 5.00E+13 0.0 0.0 ! Miller 1992 c+ch3=c2h2+h 5.00E+13 0.0 0.0 ! Miller 1992 c+ch2=c2h+h 5.00E+13 0.0 0.0 ! Miller 1992 ch2o+oh=hco+h2o 3.43E+09 1.18 -447.0 ! Miller 1992 ch2o+h=hco+h2 2.19E+08 1.77 3000.0 ! Miller 1992 ch2o+m=hco+h+m 3.31E+16 0.0 81000.0 ! Miller 1992 ch2o+o=hco+oh 1.80E+13 0.0 3080.0 ! Miller 1992 hco+o2=ho2+co 7.58E+12 0.0 410.0 ! Timonen 1988 hco+m=h+co+m 1.86E+17 -1.0 17000.0 ! Timonen 1987 h2o/5.0/ h2/1.87/ co2/3.0/ co/1.87/ ch4/2.81/ hco+oh=h2o+co 1.00E+14 0.0 0.0 ! Miller 1992 hco+h=co+h2 1.19E+13 0.25 0.0 ! Miller 1992 hco+o=co+oh 3.00E+13 0.0 0.0 ! Miller 1992 hco+o=co2+h 3.00E+13 0.0 0.0 ! Miller 1992 co+oh=co2+h 9.42E+03 2.25 -2351.0 ! (g) co+o+m=co2+m 6.17E+14 0.0 3000.0 ! Miller 1992 co+o2=co2+o 2.53E+12 0.0 47688.0 ! Miller 1992 co+ho2=co2+oh 5.80E+13 0.0 22934.0 ! Miller 1992 c2h6+ch3=c2h5+ch4 5.50E-01 4.0 8300.0 ! Miller 1992 c2h6+h=c2h5+h2 5.40E+02 3.5 5210.0 ! Miller 1992 c2h6+o=c2h5+oh 3.00E+07 2.0 5115.0 ! Miller 1992 c2h6+oh=c2h5+h2o 7.23E+06 2.0 864.0 ! Baulch 1992 c2h5+h=c2h4+h2 1.25E+14 0.0 8000.0 ! Marinov 1995 c2h5+h=ch3+ch3 3.00E+13 0.0 0.0 ! Warnatz 1984 c2h5+h=c2h6 1.00E+14 0.0 0.0 ! Marinov 1996 c2h5+oh=c2h4+h2o 4.00E+13 0.0 0.0 ! Marinov 1995 c2h5+o=ch3+ch2o 1.00E+14 0.0 0.0 ! Herron 1988 c2h5+ho2=ch3+ch2o+oh 3.00E+13 0.0 0.0 ! Marinov 1995 c2h5+o2=c2h4+ho2 3.00E+20 -2.86 6760.0 ! Marinov 1995 c2h4+h=c2h3+h2 3.36E-07 6.0 1692.0 ! Dagaut 1990 c2h4+oh=c2h3+h2o 2.02E+13 0.0 5936.0 ! Miller 1992 c2h4+o=ch3+hco 1.02E+07 1.88 179.0 ! Baulch 1994 c2h4+o=ch2hco+h 3.39E+06 1.88 179.0 ! Baulch 1994 c2h4+ch3=c2h3+ch4 6.62E+00 3.7 9500.0 ! Marinov 1995 c2h4+h (+m)=c2h5(+m) 1.08E+12 0.454 1822.0 ! Feng 1993 low / 1.112E+34 -5.0 4448.0 / ! (h) troe / 1.0 1.0E-15 95.0 200.0 / h2o /5.0/ h2/2.0/ co2/3.0/ co/2.0/ c2h4(+m)=c2h2+h2(+m) 1.8E+13 0.0 76000. ! Towell 1961 low / 1.5E+15 0.0 55443. / ! Kiefer 1983 c2h4(+m)=c2h3+h(+m) 2.00E+16 0.0 110000. ! Dean 1985 low / 1.4E+15 0.0 81833. / ! Kiefer 1983 c2h3+h=c2h2+h2 4.00E+13 0.0 0.0 ! Miller 1992 c2h3+o=ch2co+h 3.00E+13 0.0 0.0 ! Miller 1992 c2h3+o2=ch2o+hco 1.70E+29 -5.312 6500. ! Marinov 1998 c2h3+o2=ch2hco+o 3.50E+14 -0.611 5260. ! Marinov 1998 c2h3+o2=c2h2+ho2 2.12E-06 6.0 9484.0 ! cfm/nmm 1996 c2h3+oh=c2h2+h2o 2.00E+13 0.0 0.0 ! Miller 1992 c2h3+c2h=c2h2+c2h2 3.00E+13 0.0 0.0 ! Miller 1992 c2h3+ch=ch2+c2h2 5.00E+13 0.0 0.0 ! Miller 1992 c2h3+ch3=ac3h5+h 4.73E+02 3.7 5677.0 ! (i) c2h3+ch3=c3h6 4.46E+56 -13.0 13865.0 ! (i) c2h3+ch3=c2h2+ch4 2.00E+13 0.0 0.0 ! Fahr 1991 c2h3+c2h2=ch2chcch+h 2.00E+12 0.0 5000.0 ! Miller 1992 c2h3+c2h4=ch2chchch2+h 5.00E+11 0.0 7304.0 ! Tsang 1986 c2h3+c2h3=ch2chcch2+h 7.00E+13 0.0 0.0 ! Fahr 1991 c2h3+c2h3=c2h4+c2h2 1.45E+13 0.0 0.0 ! Fahr 1991 c2h2+oh=c2h+h2o 3.37E+07 2.0 14000.0 ! Miller 1992 c2h2+oh=hccoh+h 5.04E+05 2.3 13500.0 ! Miller 1992 c2h2+oh=ch2co+h 2.18E-04 4.5 -1000.0 ! Miller 1992 dup c2h2+oh=ch2co+h 2.00E+11 0.0 0.0 ! Vandooren 1977 dup c2h2+oh=ch3+co 4.83E-04 4.0 -2000.0 ! Miller 1992 hccoh+h=ch2co+h 1.00E+13 0.0 0.0 ! Miller 1992 c2h2+o=ch2+co 6.12E+06 2.0 1900.0 ! (j) c2h2+o=hcco+h 1.43E+07 2.0 1900.0 ! (j) c2h2+o=c2h+oh 3.16E+15 -0.6 15000.0 ! Miller 1992 c2h2+ch3=c2h+ch4 1.81E+11 0.0 17289.0 ! Tsang 1986 c2h2+o2=hcco+oh 4.00E+07 1.5 30100. ! Marinov 1998 c2h2+m=c2h+h+m 4.20E+16 0.0 107000.0 ! Miller 1992 c2h2+h (+m)=c2h3(+m) 3.11E+11 0.58 2589.0 ! Knyazev 1995 low / 2.25E+40 -7.269 6577.0 / ! (k) troe /1.0 1.0E-15 675.0 1.0E+15 / h2o /5.0/ h2/2.0/ co2/3.0/ co/2.0/ ch3hco+oh=ch3co+h2o 5.37E+10 0.73 -1110.0 ! Marinov 1995 ch3hco+h=ch3co+h2 4.09E+09 1.16 2400.0 ! Marinov 1995 ch3hco+o=ch3co+oh 5.89E+12 0.0 1810.0 ! Marinov 1995 ch3hco+ho2=ch3co+h2o2 1.70E+12 0.0 10700.0 ! Marinov 1995 ch3hco+o2=ch3co+ho2 2.00E+13 0.5 42200.0 ! Marinov 1995 ch3hco+ch3=ch3co+ch4 2.00E-06 5.64 2464.0 ! Marinov 1996 ch2hco+h=ch2co+h2 4.00E+13 0.0 0.0 ! Marinov 1996 ch2hco+o=ch2o+hco 1.00E+14 0.0 0.0 ! Marinov 1996 ch2hco+oh=ch2co+h2o 3.00E+13 0.0 0.0 ! Marinov 1996 ch2hco+o2=ch2o+co+oh 3.00E+10 0.0 0.0 ! Baulch 1992 ch2hco+ch3=>c2h5+co+h 4.90E+14 -0.50 0.0 ! (l) ch2hco=ch2co+h 3.95E+38 -7.649 45115.0 ! Marinov 1995 chocho(+m)=ch2o+co(+m) 4.27E+12 0.0 50600.0 ! Marinov 1995 low / 8.91E+16 0.0 49200.0 / ! Marinov 1995 chocho=co+co+h2 4.07E+42 -8.5 69278.0 ! (m) chocho+oh=hco+co+h2o 1.00E+13 0.0 0.0 ! Marinov 1995 chocho+o=hco+co+oh 7.24E+12 0.0 1970.0 ! Marinov 1995 chocho+h=ch2o+hco 1.00E+12 0.0 0.0 ! Marinov 1995 chocho+ho2=hco+co+h2o2 1.70E+12 0.0 10700.0 ! Marinov 1995 chocho+ch3=hco+co+ch4 1.74E+12 0.0 8440.0 ! Marinov 1995 chocho+o2=hco+co+ho2 1.00E+14 0.0 37000.0 ! Marinov 1995 ch3co(+m)=ch3+co(+m) 3.00E+12 0.0 16722.0 ! Warnatz 1984 low / 1.20E+15 0.0 12518.0 / ! Warnatz 1984 ch2co+o=co2+ch2 1.75E+12 0.0 1350.0 ! Marinov 1995 ch2co+h=ch3+co 7.00E+12 0.0 3011.0 ! Warnatz 1984 ch2co+h=hcco+h2 2.00E+14 0.0 8000.0 ! (n) ch2co+o=hcco+oh 1.00E+13 0.0 8000.0 ! Miller 1992 ch2co+oh=hcco+h2o 1.00E+13 0.0 2000.0 ! Miller 1992 (o) ch2co+oh=ch2oh+co 3.73E+12 0.0 -1013.0 ! Brown 1989 ch2co(+m)=ch2+co(+m) 3.00E+14 0.0 70980.0 ! Miller 1992 low / 3.60E+15 0.0 59270.0 / ! Miller 1992 c2h+h2=c2h2+h 4.09E+05 2.39 864.3 ! Miller 1992 c2h+o=ch+co 5.00E+13 0.0 0.0 ! Miller 1992 c2h+oh=hcco+h 2.00E+13 0. 0.0 ! Miller 1992 c2h+oh=c2+h2o 4.00E+07 2.0 8000.0 ! Miller 1992 c2h+o2=co+co+h 9.04E+12 0.0 -457.0 ! Opansky 1993 c2h+c2h2=c4h2+h 9.64E+13 0.0 0.0 ! Farhat 1993 c2h+c2h4=ch2chcch+h 1.20E+13 0.0 0.0 ! Tsang 1986 hcco+c2h2=h2ccch+co 1.00E+11 0.0 3000.0 ! Miller 1992 hcco+h=ch2(s)+co 1.00E+14 0.0 0.0 ! Miller 1992 hcco+o=h+co+co 8.00E+13 0.0 0.0 ! Peeters 1995 hcco+o=ch+co2 2.95E+13 0.0 1113.0 ! Peeters 1995 hcco+o2=hco+co+o 2.50E+08 1.0 0.0 ! Marinov 1998 hcco+o2=co2+hco 2.40E+11 0.0 -854.0 ! Marinov 1998 hcco+ch=c2h2+co 5.00E+13 0.0 0.0 ! Miller 1992 hcco+hcco=c2h2+co+co 1.00E+13 0.0 0.0 ! Miller 1992 hcco+oh=c2o+h2o 3.00E+13 0.0 0.0 ! Miller 1992 c2o+h=ch+co 1.00E+13 0.0 0.0 ! Miller 1992 c2o+o=co+co 5.00E+13 0.0 0.0 ! Miller 1992 c2o+oh=co+co+h 2.00E+13 0.0 0.0 ! Miller 1992 c2o+o2=co+co+o 2.00E+13 0.0 0.0 ! Miller 1992 c2+h2=c2h+h 4.00E+05 2.4 1000.0 ! Miller 1992 c2+o2=co+co 5.00E+13 0.0 0.0 ! Miller 1992 c2+oh=c2o+h 5.00E+13 0.0 0.0 ! Miller 1992 c3h8(+m)=c2h5+ch3(+m) 7.90E+22 -1.8 88629.0 ! Tsang 1988 low / 7.237E+27 -2.88 67448.0 / ! Al-Alami 1983 troe /1.0 1.0E-15 1500.0 1.0E+15/ h2o/5.0/ co2/3.0/ co/2.0/ h2/2.0/ c3h8+o2=ic3h7+ho2 4.00E+13 0.0 48610.0 ! Tsang 1988 c3h8+o2=nc3h7+ho2 4.00E+13 0.0 51360.0 ! Tsang 1988 c3h8+ho2=nc3h7+h2o2 4.76E+04 2.55 16492.0 ! Tsang 1988 c3h8+ho2=ic3h7+h2o2 9.64E+03 2.6 13909.0 ! Tsang 1988 c3h8+oh=nc3h7+h2o 3.16E+07 1.8 934.0 ! Cohen 1991 c3h8+oh=ic3h7+h2o 7.08E+06 1.9 -159.0 ! Cohen 1991 c3h8+o=nc3h7+oh 3.73E+06 2.4 5504.0 ! Cohen 1986 c3h8+o=ic3h7+oh 5.48E+05 2.5 3139.0 ! Cohen 1986 c3h8+h=ic3h7+h2 1.30E+06 2.4 4471.0 ! Tsang 1988 c3h8+h=nc3h7+h2 1.33E+06 2.54 6756.0 ! Tsang 1988 c3h8+ch3=nc3h7+ch4 9.04E-01 3.65 7153.0 ! Tsang 1988 c3h8+ch3=ic3h7+ch4 1.51E+00 3.46 5480.0 ! Tsang 1988 c3h8+c2h3=ic3h7+c2h4 1.00E+03 3.1 8830.0 ! Tsang 1988 c3h8+c2h3=nc3h7+c2h4 6.00E+02 3.3 10500.0 ! Tsang 1988 c3h8+c2h5=ic3h7+c2h6 1.51E+00 3.46 7470.0 ! Tsang 1988 c3h8+c2h5=nc3h7+c2h6 9.03E-01 3.65 9140.0 ! Tsang 1988 c3h8+ac3h5=c3h6+nc3h7 2.35E+02 3.3 19842.0 ! Tsang 1988 c3h8+ac3h5=c3h6+ic3h7 7.83E+01 3.3 18169.0 ! Tsang 1988 nc3h7(+m)=c2h4+ch3(+m) 1.23E+13 -0.1 30202.0 ! Bencsura 1992 low / 5.485E+49 -10.0 35766.0 / ! Bencsura 1992 troe / 2.17 1.0E-15 251.0 1185.0 / h2o /5.0/ h2/2.0/ co2/3.0/ co/2.0/ nc3h7+o2=c3h6+ho2 3.58E+09 0.0 -3532.0 ! Dagaut 1992 ic3h7+o2=c3h6+ho2 6.10E+20 -2.86 7910.0 ! (p) c3h6+h(+m)=ic3h7(+m) 5.70E+09 1.16 874.0 ! Seakins 1993 low / 1.64E+54 -11.1 9364.0 / ! Marinov 1996 troe / 1.0 1.0E-15 260.0 3000.0 / h2o /5.0/ h2/2.0/ co2/3.0/ co/2.0/ ic3h7+h=c2h5+ch3 5.00E+13 0.0 0.0 ! Tsang 1988 nc3h7+h=c2h5+ch3 1.00E+14 0.0 0.0 ! Tsang 1988 c3h6=pc3h5+h 7.58E+14 0.0 101300.0 ! Dagaut 1992 c3h6=sc3h5+h 1.45E+15 0.0 98060.0 ! Dagaut 1992 c3h6=c2h2+ch4 2.50E+12 0.0 70000.0 ! Hidaka 1992 c3h6=ac3h4+h2 3.00E+13 0.0 80000.0 ! Hidaka 1992 c3h6+ho2=ac3h5+h2o2 9.64E+03 2.6 13910.0 ! Tsang 1991 c3h6+oh+o2=ch3hco+ch2o+oh 3.00E+10 0.0 -8280.0 ! Dagaut 1992 c3h6+oh=ac3h5+h2o 3.12E+06 2.0 -298.0 ! Tsang 1991 c3h6+oh=sc3h5+h2o 1.11E+06 2.0 1451.0 ! Tsang 1991 c3h6+oh=pc3h5+h2o 2.11E+06 2.0 2778.0 ! Tsang 1991 c3h6+o=ch3chco+h+h 5.01E+07 1.76 76.0 ! Tsang 1991 c3h6+o=c2h5+hco 1.58E+07 1.76 -1216.0 ! Tsang 1991 c3h6+o=ac3h5+oh 5.24E+11 0.7 5884.0 ! Tsang 1991 c3h6+o=pc3h5+oh 1.20E+11 0.7 8959.0 ! Tsang 1991 c3h6+o=sc3h5+oh 6.03E+10 0.7 7632.0 ! Tsang 1991 c3h6+h=c2h4+ch3 7.23E+12 0.0 1302.0 ! Tsang 1991 c3h6+h=ac3h5+h2 1.73E+05 2.5 2492.0 ! Tsang 1991 c3h6+h=sc3h5+h2 4.09E+05 2.5 9794.0 ! Tsang 1991 c3h6+h=pc3h5+h2 8.04E+05 2.5 12284.0 ! Tsang 1991 c3h6+o2=pc3h5+ho2 2.00E+13 0.0 47600.0 ! Dagaut 1992 c3h6+o2=sc3h5+ho2 2.00E+13 0.0 44000.0 ! Dagaut 1992 c3h6+o2=ac3h5+ho2 2.29E+12 0.0 39200.0 ! Dagaut 1992 c3h6+ch3=ac3h5+ch4 2.22E+00 3.5 5675.0 ! Tsang 1991 c3h6+ch3=sc3h5+ch4 8.43E-01 3.5 11656.0 ! Tsang 1991 c3h6+ch3=pc3h5+ch4 1.35E+00 3.5 12848.0 ! Tsang 1991 c3h6+hco=ac3h5+ch2o 1.08E+07 1.9 17010.0 ! Tsang 1991 ch3chco+oh=ch2chco+h2o 4.00E+06 2.0 0.0 ! (q) ch3chco+o=ch2chco+oh 7.60E+08 1.5 8500.0 ! (q) ch3chco+h=ch2chco+h2 2.00E+05 2.5 2500.0 ! (q) ch3chco+h=c2h5+co 2.00E+13 0.0 2000.0 ! (r) ch3chco+o=ch3+hco+co 3.00E+07 2.0 0.0 ! (s) ch2chcho+oh=ch2chco+h2o 1.00E+13 0.0 0.0 ! (t) ch2chcho+o=ch2chco+oh 7.24E+12 0.0 1970.0 ! (t) ch2chcho+o=ch2co+hco+h 5.01E+07 1.76 76.0 ! (s) ch2chcho+h=ch2chco+h2 3.98E+13 0.0 4200.0 ! (t) ch2chcho+h=c2h4+hco 2.00E+13 0.0 3500.0 ! (r) ch2chcho+o2=ch2chco+ho2 3.00E+13 0.0 36000.0 ! (u) ch2chco=c2h3+co 1.00E+14 0.0 34000.0 ! (v) ch2chco+o=c2h3+co2 1.00E+14 0.0 0.0 ! (w) ac3h5+o2=ch2chcho+oh 1.82E+13 -0.41 22859.0 ! Bozzelli 1993 ac3h5+o2=ac3h4+ho2 4.99E+15 -1.4 22428.0 ! Bozzelli 1993 ac3h5+o2=ch2hco+ch2o 1.06E+10 0.34 12838.0 ! Bozzelli 1993 ac3h5+o2=c2h2+ch2o+oh 2.78E+25 -4.8 15468.0 ! Bozzelli 1993 ac3h5+ho2=ch2chcho+h+oh 1.00E+13 0.0 0.0 ! Tsang 1991 ac3h5+oh=ac3h4+h2o 1.00E+13 0.0 0.0 ! Tsang 1991 ac3h5+h=ac3h4+h2 5.00E+13 0.0 0.0 ! Tsang 1991 (x) ac3h5+h=c3h6 1.88E+26 -3.6 5468.0 ! (y) ac3h5+o=ch2chcho+h 1.81E+14 0.0 0.0 ! Slagle 1992 ac3h5+ch3=ac3h4+ch4 3.02E+12 -0.32 -131.0 ! Tsang 1991 ac3h5+c2h2=c-c5h6+h 2.95E+32 -5.83 25733.0 ! (y) ac3h5+ch3=c4h8-1 1.76E+50 -11.0 18600.0 ! (y) ac3h5+c2h3=c-c5h6+h+h 1.59E+65 -14.0 61265.0 ! (y) pc3h5+o2=ch3hco+hco 1.09E+23 -3.29 3892.0 ! (z) pc3h5+o2=ch3chco+h+o 1.60E+15 -0.78 3135.0 ! (z) pc3h5+o=ch3chco+h 1.00E+14 0.0 0.0 ! (aa) pc3h5+h=pc3h4+h2 2.00E+13 0.0 0.0 ! (aa) pc3h5+oh=pc3h4+h2o 1.00E+13 0.0 0.0 ! (aa) pc3h5+h=ac3h5+h 1.00E+14 0.0 0.0 ! Marinov 1996 sc3h5+h=ac3h5+h 1.00E+14 0.0 0.0 ! Marinov 1996 sc3h5+o2=ch3co+ch2o 1.09E+22 -3.29 3892.0 ! (z) sc3h5+o=ch2co+ch3 1.00E+14 0.0 0.0 ! (aa) sc3h5+h=pc3h4+h2 4.00E+13 0.0 0.0 ! (aa) sc3h5+oh=pc3h4+h2o 2.00E+13 0.0 0.0 ! (aa) ac3h4+h=h2ccch+h2 2.00E+07 2.0 5000.0 ! Marinov 1998 ac3h4+o=c2h4+co 1.34E+07 1.88 179.0 ! (bb) ac3h4+oh=h2ccch+h2o 1.00E+07 2.0 1000.0 ! Marinov 1998 ac3h4+ch3=h2ccch+ch4 1.50E+00 3.5 5600.0 ! Marinov 1998 ac3h4=pc3h4 1.48E+13 0.0 60401. ! Lifshitz 1975 pc3h4+h=h2ccch+h2 2.00E+07 2.0 5000.0 ! Marinov 1998 pc3h4+o=c2h4+co 1.50E+13 0.0 2102.0 ! Warnatz84 (cc) pc3h4+oh=h2ccch+h2o 1.00E+07 2.0 1000.0 ! Marinov 1998 pc3h4+ch3=h2ccch+ch4 1.50E+00 3.5 5600.0 ! Marinov 1998 pc3h4+h=ch3+c2h2 5.12E+10 1.0 2060.0 ! Marinov 1998 pc3h4+h(+m)=sc3h5(+m) 6.50E+12 0.0 2000.0 ! Wagner 1972 low / 8.45E+39 -7.27 6577.0 / ! (dd) ac3h4+h(+m)=ac3h5(+m) 1.20E+11 0.69 3007.0 ! Tsang 1992 low / 5.56E+33 -5.0 4448.0 / ! (ee) ac3h4+h(+m)=sc3h5(+m) 8.49E+12 0.0 2000.0 ! Wagner 1972 low / 1.11E+34 -5.0 4448.0 / ! (ee) h2ccch+o2=ch2co+hco 3.00E+10 0.0 2868.0 ! Miller 1992 h2ccch+o=ch2o+c2h 2.00E+13 0.0 0.0 ! Miller 1992 h2ccch+h=c3h2+h2 5.00E+13 0.0 3000.0 ! Miller 1992 h2ccch+oh=c3h2+h2o 2.00E+13 0.0 0.0 ! Miller 1992 h2ccch+c2h3=c-c5h5+h 9.63E+40 -7.8 28820.0 ! Marinov 1996 h2ccch+ch3=ch3chcch2 5.00E+12 0.0 0.0 ! Wu 1987 h2ccch+ch3=ch3ch2cch 5.00E+12 0.0 0.0 ! Wu 1987 h2ccch+ch=hcchcch+h 7.00E+13 0.0 0.0 ! Miller 1992 h2ccch+ch=h2cccch+h 7.00E+13 0.0 0.0 ! Miller 1992 h2ccch+h(+m)=ac3h4(+m) 1.66E+15 -0.37 0.0 ! (ff) low / 3.36E+45 -8.52 6293.0 / ! Kiefer 1995 (gg) h2o/5.0/ h2/2.0/ co2/3.0/ co/2.0/ o2/2.0/ c2h2/2.0/ h2ccch+h(+m)=pc3h4(+m) 1.66E+15 -0.37 0.0 ! (ff) low / 8.78E+45 -8.9 7974.0 / ! Kiefer 1995 (gg) h2o /5.0/ h2/2.0/ co2/3.0/ co/2.0/ o2/2.0/ c2h2/2.0/ h2ccch+h2ccch=c6h6 5.562e20 -2.535 1692.0 ! Marinov 1998 h2ccch+ac3h5=fulvene+h+h 5.562e20 -2.535 1692.0 ! Marinov 1998 h2ccch+h2ccch=c6h5+h 2.00e12 0.0 0.0 ! Marinov 1998 c3h2+o2=hcco+co+h 5.00E+13 0.0 0.0 ! Miller 1992 c3h2+oh=c2h2+hco 5.00E+13 0.0 0.0 ! Miller 1992 chchcho+o2=hco+chocho 3.00E+12 0.0 0.0 ! (hh) chchcho=c2h2+hco 1.00E+14 0.0 33000.0 ! (ii) chchcho+h=ch2chco+h 1.00E+14 0.0 0.0 ! Marinov 1996 chchcho+oh=hcccho+h2o 1.00E+13 0.0 0.0 ! (aa) chchcho+h=hcccho+h2 2.00E+13 0.0 0.0 ! (aa) hcccho+h=c2h2+hco 1.00E+14 0.0 3000.0 ! (jj) hcccho+oh=hccco+h2o 1.00E+13 0.0 0.0 ! (t) hcccho+h=hccco+h2 4.00E+13 0.0 4200.0 ! (t) hccco+o2=hco+co+co 1.40E+09 1.0 0.0 ! (kk) hccco+h=c2h2+co 1.00E+14 0.0 0.0 ! (kk) c4h10=c2h5+c2h5 2.00E+16 0.0 81300.0 ! Pitz 1991 c4h10=nc3h7+ch3 1.74E+17 0.0 85700.0 ! Pitz 1991 c4h10=pc4h9+h 1.00E+14 0.0 100000.0 ! Pitz 1991 c4h10=sc4h9+h 1.00E+14 0.0 100000.0 ! Pitz 1991 c4h10+o2=pc4h9+ho2 2.50E+13 0.0 49000.0 ! Pitz 1991 c4h10+o2=sc4h9+ho2 4.00E+13 0.0 47600.0 ! Pitz 1991 c4h10+ac3h5=pc4h9+c3h6 7.94E+11 0.0 20500.0 ! Pitz 1991 c4h10+ac3h5=sc4h9+c3h6 3.16E+11 0.0 16400.0 ! Pitz 1991 c4h10+ch3=pc4h9+ch4 5.00E+11 0.0 13600.0 ! Marinov 1998 c4h10+ch3=sc4h9+ch4 4.30E+11 0.0 10500.0 ! Marinov 1998 c4h10+h=pc4h9+h2 2.84E+05 2.54 6050.0 ! Marinov 1998 c4h10+h=sc4h9+h2 5.68E+05 2.40 3765.0 ! Marinov 1998 c4h10+oh=pc4h9+h2o 4.13E+07 1.73 753.0 ! Pitz 1991 c4h10+oh=sc4h9+h2o 7.23E+07 1.64 -247.0 ! Pitz 1991 c4h10+o=pc4h9+oh 1.13E+14 0.0 7850.0 ! Pitz 1991 c4h10+o=sc4h9+oh 5.62E+13 0.0 5200.0 ! Pitz 1991 c4h10+ho2=pc4h9+h2o2 1.70E+13 0.0 20460.0 ! Pitz 1991 c4h10+ho2=sc4h9+h2o2 1.12E+13 0.0 17700.0 ! Pitz 1991 sc4h9(+m)=c3h6+ch3(+m) 2.14E+12 0.65 30856.0 ! Knyazev 1996 low /6.323e58 -12.85 35567./ h2o/5./ h2/2./ co2/3./ co/2./ sc4h9=c4h8-1+h 2.00E+13 0.0 40400.0 ! Pitz 1991 sc4h9=c4h8-2+h 5.01E+12 0.0 37900.0 ! Pitz 1991 pc4h9(+m)=c2h5+c2h4(+m) 1.06e13 0.0 27828.0 ! Knyazev 1996 low / 1.897e55 -11.91 32263./ h2o/5./ h2/2.0/ co2/3.0/ co/2.0/ pc4h9=c4h8-1+h 1.26E+13 0.0 38600.0 ! Pitz 1991 c4h8-1=c2h3+c2h5 1.00E+19 -1.0 96770.0 ! Pitz 1991 c4h8-1=h+c4h7 4.11E+18 -1.0 97350.0 ! Pitz 1991 c4h8-1+ch3=c4h7+ch4 1.00E+11 0.0 7300.0 ! Pitz 1991 c4h8-1+h=c4h7+h2 5.00E+13 0.0 3900.0 ! Pitz 1991 c4h8-1+o=nc3h7+hco 1.80E+05 2.5 -1029.0 ! Pitz 1991 c4h8-1+o=ch2chcho+ch3+h 9.67E+04 2.5 -1029.0 ! Pitz 1991 c4h8-1+oh=c4h7+h2o 2.25E+13 0.0 2217.0 ! Pitz 1991 c4h8-1+ac3h5=c4h7+c3h6 7.90E+10 0.0 12400.0 ! Pitz 1991 c4h8-1+o2=c4h7+ho2 4.00E+12 0.0 33200.0 ! Pitz 1991 c4h8-2=h+c4h7 4.11E+18 -1.0 97350.0 ! Pitz 1991 c4h8-2+ch3=c4h7+ch4 1.00E+11 0.0 8200.0 ! Pitz 1991 c4h8-2+h=c4h7+h2 5.00E+13 0.0 3800.0 ! Pitz 1991 c4h8-2+o=ic3h7+hco 2.79E+06 2.12 -1775.0 ! Pitz 1991 c4h8-2+oh=c4h7+h2o 3.90E+13 0.0 2217.0 ! Pitz 1991 c4h8-2+o=ch3co+c2h5 1.53E+07 1.87 -1476.0 ! Adusei 1994 c4h8-2+o=ch3+ch3chco+h 8.22E+06 1.87 -1476.0 ! Adusei 1994 c4h8-2+o2=c4h7+ho2 8.00E+13 0.0 37400.0 ! Pitz 1991 c4h7=ch2chchch2+h 1.00E+14 0.0 55000.0 ! Pitz 1991 c4h7+oh=ch2chchch2+h2o 1.00E+13 0.0 0.0 ! Pitz 1991 c4h7+ch3=ch2chchch2+ch4 8.00E+12 0.0 0.0 ! Pitz 1991 c4h7+ac3h5=c3h6+ch2chchch2 6.31E+12 0.0 0.0 ! Pitz 1991 c4h7+o2=ch2chchch2+ho2 1.00E+09 0.0 0.0 ! Pitz 1991 c4h7+h=ch2chchch2+h2 3.16E+13 0.0 0.0 ! Pitz 1991 ch2chchch2+oh=ch2chchch+h2o 2.00E+07 2.0 5000.0 ! Miller 1992 ch2chchch2+oh=ch2chcch2+h2o 2.00E+07 2.0 2000.0 ! Miller 1992 ch2chchch2+o=hco+ac3h5 6.02E+08 1.45 -858.0 ! Adusei 1993 ch2chchch2+o=ch2hco+c2h3 1.00E+12 0.0 0.0 ! Pitz 1991 ch2chchch2+h=ch2chchch+h2 3.00E+07 2.0 13000.0 ! Miller 1992 ch2chchch2+h=ch2chcch2+h2 3.00E+07 2.0 6000.0 ! Miller 1992 ch3ch2cch+oh=ch3chcch+h2o 1.00E+07 2.0 2000.0 ! (q) ch3ch2cch+h=c2h5+c2h2 1.00E+14 0.0 3000.0 ! (jj) ch3chcch2+oh=ch2chcch2+h2o 2.00E+07 2.0 1000.0 ! (q) ch3chcch2+oh=ch3ccch2+h2o 1.00E+07 2.0 2000.0 ! (ll) ch3chcch2+oh=ch3chcch+h2o 2.00E+07 2.0 2500.0 ! (ll) ch3chcch2+h=ch2chcch2+h2 5.00E+07 2.0 5000.0 ! (q) ch3chcch2+h=ch3ccch2+h2 1.50E+07 2.0 6000.0 ! (ll) ch3chcch2+h=ch3chcch+h2 3.00E+07 2.0 6500.0 ! (ll) ch3chcch2+h=ch3+ac3h4 2.00E+13 0.0 2000.0 ! (r) ch3chcch+h=ch3+h2ccch 1.00E+14 0.0 0.0 ! Marinov 1996 ch3chcch+o2=ch3chco+hco 4.16E+10 0.0 2510.0 ! Slagle 1992 ch3chcch+oh=ch2chcch+h2o 3.00E+13 0.0 0.0 ! (mm) ch2chcch2+h=ch3+h2ccch 1.00E+14 0.0 0.0 ! (nn) ch2chcch2+h=ch3ccch2+h 3.00E+13 0.0 0.0 ! (nn) ch2chcch2+c2h2=c6h6+h 3.00E+11 0.0 14900.0 ! Marinov 1996 ch3ccch2+h=ch3+h2ccch 1.00E+14 0.0 0.0 ! Marinov 1996 ch3ccch2+o2=ch3co+ch2co 4.16E+10 0.0 2510.0 ! Marinov 1996 ch3ccch2+h=h2cccch2+h2 1.00E+14 0.0 8000.0 ! (mm) ch3ccch2+oh=h2cccch2+h2o 1.00E+13 0.0 0.0 ! (mm) ch2chchch+h=ch2chcch2+h 1.00E+14 0.0 0.0 ! Miller 1992 ch2chchch+oh=ch2chcch+h2o 2.00E+07 2.0 1000.0 ! Miller 1992 ch2chchch+h=ch2chcch+h2 3.00E+07 2.0 1000.0 ! Miller 1992 ch2chchch+c2h2=c6h6+h 1.60E+16 -1.33 5400.0 ! Wang 1994 ch3chcch(+m)=ch2chcch+h(+m) 1.00E+13 0.0 49000.0 ! (pp) low / 2.00E+14 0.0 41000.0 / ! (pp) ch3ccch2(+m)=h2cccch2+h(+m) 1.00E+13 0.0 56000.0! Marinov 1996 low / 2.00E14 0.0 48000.0/ ! Marinov 1996 ch2chcch2(+m)=ch2chcch+h(+m) 1.00E+14 0.0 50000.0 ! Miller 1992 low / 2.00E+15 0.0 42000.0 / ! Miller 1992 ch2chchch(+m)=ch2chcch+h(+m) 1.00E+14 0.0 37000.0 ! Miller 1992 low / 1.00E+14 0.0 30000.0 / ! Miller 1992 ch2chchch+o2=chchcho+ch2o 1.00E+12 0.0 0.0 ! (qq) ch2chchch+o2=ch2chcch+ho2 1.00E+07 2.0 10000.0 ! (rr) ch3ccch2+h2ccch=c6h5ch2+h 3.00E+12 0.0 0.0 ! Marinov 1996 ch3chcch+h2ccch=c6h5ch2+h 3.00E+12 0.0 0.0 ! Marinov 1996 ch3ccch2+ch3ccch2=ch3c6h4ch2+h 3.00E+12 0.0 0.0 ! Marinov 1996 ch3chcch+ch3chcch=ch3c6h4ch2+h 3.00E+12 0.0 0.0 ! Marinov 1996 h2cccch2+oh=h2cccch+h2o 2.00E+07 2.0 2000.0 ! (ss) h2cccch2+h=h2cccch+h2 3.00E+07 2.0 6000.0 ! (ss) ch2chcch+oh=hcchcch+h2o 7.50E+06 2.0 5000.0 ! Miller 1992 ch2chcch+h=hcchcch+h2 2.00E+07 2.0 15000.0 ! Miller 1992 ch2chcch+oh=h2cccch+h2o 1.00E+07 2.0 2000.0 ! Miller 1992 ch2chcch+h=h2cccch+h2 3.00E+07 2.0 5000.0 ! Miller 1992 hcchcch+h=h2cccch+h 1.00E+14 0.0 0.0 ! Miller 1992 hcchcch+c2h2=c6h5 9.60E+70 -17.77 31300.! Wang 1994 hcchcch+o2=hcccho+hco 3.00E+12 0.0 0.0 ! (tt) h2cccch+o2=ch2co+hcco 1.00E+12 0.0 0.0 ! Miller 1992 h2cccch+oh=c4h2+h2o 3.00E+13 0.0 0.0 ! Miller 1992 h2cccch+o=ch2co+c2h 2.00E+13 0.0 0.0 ! Miller 1992 h2cccch+o=h2c4o+h 2.00E+13 0.0 0.0 ! Miller 1992 h2cccch+h=c4h2+h2 5.00E+13 0.0 0.0 ! Miller 1992 h2cccch+ch2=ac3h4+c2h 2.00E+13 0.0 0.0 ! Miller 1992 h2cccch+c2h2=c6h5 3.00E+11 0.0 14900.0 ! (uu) h2cccch(+m)=c4h2+h(+m) 1.00E+14 0.0 47000.0 ! Marinov 1998 low / 2.0E+15 0.0 40000.0/ ! Marinov 1998 hcchcch(+m)=c4h2+h(+m) 1.00E+14 0.0 36000.0 ! Miller 1992 low / 1.00E+14 0.0 30000.0 / ! Miller 1992 c4h2+ch2=c5h3+h 1.30E+13 0.0 4326.0 ! Miller 1992 c4h2+ch=c5h2+h 1.00E+14 0.0 0.0 ! Miller 1992 c4h2+ch2(s)=c5h3+h 3.00E+13 0.0 0.0 ! Miller 1992 c4h2+c2h=c6h2+h 9.60E+13 0.0 0.0 ! Marinov 1996 c4h2+oh=h2c4o+h 6.66E+12 0.0 -410.0 ! Miller 1992 c4h2+o=c3h2+co 1.20E+12 0.0 0.0 ! Miller 1992 h2c4o+h=c2h2+hcco 5.00E+13 0.0 3000.0 ! Miller 1992 h2c4o+oh=ch2co+hcco 1.00E+07 2.0 2000.0 ! Miller 1992 l-c5h8+oh=l-c5h7+h2o 7.00E+06 2.0 0.0 ! (q) l-c5h8+h=l-c5h7+h2 7.00E+06 2.0 5000.0 ! (q) l-c5h8+h=ac3h5+c2h4 3.35E+08 1.5 2000.0 ! (r) c-c5h7=c-c5h6+h 3.16E+15 0.0 36000.0 ! Arends 1993 c-c5h7=l-c5h7 3.16E+15 0.0 39500.0 ! Arends 1993 l-c5h7+o=ch2chcho+c2h3 2.00E+14 0.0 0.0 ! Marinov 1996 l-c5h7+h=l-c5h8 1.00E+14 0.0 0.0 ! Marinov 1996 c-c5h6+o2=c-c5h5+ho2 5.00E+13 0.0 35400.0 ! (vv) c-c5h6+ho2=c-c5h5+h2o2 1.99E+12 0.0 11660.0 ! Emdee 1992 c-c5h6+oh=c-c5h5+h2o 3.43E+09 1.18 -447.0 ! Emdee 1992 c-c5h6+o=c-c5h5+oh 1.81E+13 0.0 3080.0 ! Emdee 1992 c-c5h6+h=c-c5h5+h2 2.19E+08 1.77 3000.0 ! Emdee 1992 c-c5h6+ch3=c-c5h5+ch4 3.11E+11 0.0 5500.0 ! (ww) c-c5h6+c2h3=c-c5h5+c2h4 6.00E+12 0.0 0.0 ! Emdee 1992 c-c5h6+ch2chchch=c-c5h5+ch2chchch2 6.00E+12 0.0 0.0 ! Emdee 1992 c-c5h6+c6h5o=c-c5h5+c6h5oh 3.16E+11 0.0 8000.0 ! Emdee 1992 c-c5h5+h=c-c5h6 2.00E+14 0.0 0.0 ! Marinov 1996 c-c5h5+o=c-c5h4o+h 1.00E+14 0.0 0.0 ! Marinov 1996 c-c5h5+ho2=c-c5h5o+oh 3.00E+13 0.0 0.0 ! Emdee 1992 c-c5h5+oh=c-c5h4oh+h 3.00E+13 0.0 0.0 ! Emdee 1992 c-c5h5+c-c5h5=c10h8+h+h 2.00E+13 0.0 8000.0 ! Marinov 1998 c-c5h5o=ch2chchch+co 2.51E+11 0.0 43900.0 ! Emdee 1992 c-c5h4oh=c-c5h4o+h 2.10E+13 0.0 48000.0 ! Emdee 1992 c-c5h4o=co+c2h2+c2h2 1.00E+15 0.0 78000.0 ! Emdee 1992 c6h6+o2=c6h5+ho2 6.30E+13 0.0 60000.0 ! Emdee 1992 c6h6+oh=c6h5+h2o 1.63E+08 1.42 1454.0 ! Baulch 1992 c6h6+oh=c6h5oh+h 6.70E+12 0.0 10592.0 ! He 1988 (xx) c6h6+o=c6h5o+h 2.40E+13 0.0 4670.0 ! Leidreiter 1989 c6h6+h=c6h5+h2 3.03E+02 3.3 5690.0 ! (yy) c6h5+h=c6h6 8.00E+13 0.0 0.0 ! Baulch 1992 c6h5+c2h4=c6h5c2h3+h 7.23E+01 3.5 8345.0 ! Yu 1994 c6h5+c2h2=c6h5c2h+h 3.98E+13 0.0 10099.0 ! Stein 1989 c6h5+oh=c6h5o+h 5.00E+13 0.0 0.0 ! Miller 1992 c6h5+o=c-c5h5+co 1.00E+14 0.0 0.0 ! Frank 1994 c6h5+o2=c6h5o+o 2.60E+13 0.0 6120.0 ! Frank 1994 c6h5+o2=oc6h4o+h 3.00E+13 0.0 8981.0 ! Frank 1994 c6h5+c6h5=biphenyl 5.00E+12 0.0 0.0 ! Fahr 1989 c6h5+c6h6=biphenyl+h 4.00E+11 0.0 4000.0 ! Fahr 1989 oc6h4o=c-c5h4o+co 1.00E+15 0.0 78000.0 ! Marinov 1996 c6h5o=co+c-c5h5 7.40E+11 0.0 43850.0 ! Frank 1994 c6h5o+h=c6h5oh 1.00E+14 0.0 0.0 ! Arends 1993 c6h5o+h=c-2*4c6h6o 1.00E+14 0.0 0.0 ! Arends 1993 c6h5oh+oh=c6h5o+h2o 2.95E+06 2.0 -1310.0 ! Knispel 1990 c6h5oh+ch3=c6h5o+ch4 1.81E+11 0.0 7716.0 ! Mulcahy 1965 c6h5oh+h=c6h5o+h2 1.58E+13 0.0 6100.0 ! Arends 1993 c6h5oh+o=c6h5o+oh 2.81E+13 0.0 7352.0 ! Emdee 1992 c6h5oh+c2h3=c2h4+c6h5o 6.00E+12 0.0 0.0 ! Emdee 1992 c6h5oh+c6h5=c6h6+c6h5o 4.91E+12 0.0 4400.0 ! Emdee 1992 c-2*4c6h6o+h=c-c5h7+co 2.51E+13 0.0 4700.0 ! Arends 1993 c6h5ch3=c6h5+ch3 1.40E+16 0.0 99800.0 ! Emdee 1992 c6h5ch3+o2=c6h5ch2+ho2 2.00E+12 0.0 39080.0 ! Ingram 1994 c6h5ch3+oh=c6h5ch2+h2o 1.26E+13 0.0 2583.0 ! Emdee 1992 c6h5ch3+o=c6h5ch2+oh 5.00E+08 1.5 8000.0 ! Emdee 1992 c6h5ch3+h=c6h5ch2+h2 3.98E+02 3.44 3120.0 ! Emdee 1992 c6h5ch3+h=c6h6+ch3 1.20E+13 0.0 5148.0 ! Emdee 1992 c6h5ch3+o=oc6h4ch3+h 1.63E+13 0.0 3418.0 ! Emdee 1992 c6h5ch3+ch3=ch4+c6h5ch2 3.16E+11 0.0 9500.0 ! Emdee 1992 c6h5ch3+c6h5=c6h6+c6h5ch2 2.10E+12 0.0 4400.0 ! Emdee 1992 c6h5ch2+h=c6h5ch3 1.80E+14 0.0 0.0 ! Emdee 1992 c6h5ch2+c6h5oh=c6h5o+c6h5ch3 1.05E+11 0.0 9500.0 ! Emdee 1992 c6h5ch2+hoc6h4ch3=oc6h4ch3+c6h5ch3 1.05E+11 0.0 9500.0 ! Emdee 1992 c6h5ch2+o=c6h5cho+h 2.50E+14 0.0 0.0 ! Emdee 1992 c6h5ch2+o=c6h5+ch2o 8.00E+13 0.0 0.0 ! Emdee 1992 c6h5ch2+ho2=c6h5cho+h+oh 2.50E+14 0.0 0.0 ! Emdee 1992 c6h5ch2+ho2=c6h5+ch2o+oh 8.00E+13 0.0 0.0 ! Emdee 1992 c6h5ch2+ch3=c6h5c2h5 1.19E+13 0.0 221.0 ! Brand 1990 c6h5ch2+h2ccch=c10h10 1.00E+10 0.0 0.0 ! (zz) c6h5ch2+c2h2=indene+h 3.20E+11 0.0 7000.0 ! (aaa) c6h5ch2+c6h5cho=c6h5ch3+c6h5co 2.77E+03 2.81 5773.0 ! Emdee 1992 c6h5ch2+oh=c6h5ch2oh 6.00E+13 0.0 0.0 ! Emdee 1992 c6h5ch2oh+oh=c6h5cho+h2o+h 8.43E+12 0.0 2583.0 ! Emdee 1992 c6h5ch2oh+h=c6h5cho+h2+h 8.00E+13 0.0 8235.0 ! Emdee 1992 c6h5ch2oh+h=c6h6+ch2oh 1.20E+13 0.0 5148.0 ! Emdee 1992 c6h5ch2oh+c6h5ch2=c6h5cho+c6h5ch3+h 2.11E+11 0.0 9500. ! Emdee92 c6h5ch2oh+c6h5=c6h5cho+c6h6+h 1.40E+12 0.0 4400.0 ! Emdee 1992 c6h5cho+o2=c6h5co+ho2 1.02E+13 0.0 38950.0 ! Emdee 1992 c6h5cho+oh=c6h5co+h2o 1.71E+09 1.18 -447.0 ! Emdee 1992 c6h5cho+h=c6h5co+h2 5.00E+13 0.0 4928.0 ! Emdee 1992 c6h5cho+h=c6h5+ch2o 2.00E+13 0.0 2000.0 ! (r) c6h5cho+h=c6h6+hco 1.20E+13 0.0 5148.0 ! Emdee 1992 c6h5cho+o=c6h5co+oh 9.04E+12 0.0 3080.0 ! Emdee 1992 c6h5cho+ch3=ch4+c6h5co 2.77E+03 2.81 5773.0 ! Emdee 1992 c6h5cho+c6h5=c6h6+c6h5co 7.01E+11 0.0 4400.0 ! Emdee 1992 c6h5co=c6h5+co 3.98E+14 0.0 29400.0 ! Emdee 1992 oc6h4ch3+h=hoc6h4ch3 2.50E+14 0.0 0.0 ! Emdee 1992 oc6h4ch3=c6h6+h+co 2.51E+11 0.0 43900.0 ! Emdee 1992 hoc6h4ch3+oh=oc6h4ch3+h2o 6.00E+12 0.0 0.0 ! Emdee 1992 hoc6h4ch3+h=oc6h4ch3+h2 1.15E+14 0.0 12400.0 ! Emdee 1992 hoc6h4ch3+h=c6h5ch3+oh 2.21E+13 0.0 7910.0 ! Emdee 1992 hoc6h4ch3+h=c6h5oh+ch3 1.20E+13 0.0 5148.0 ! Emdee 1992 c6h5c2h5+oh=c6h5c2h3+h2o+h 8.43E+12 0.0 2583. ! Emdee 1992 c6h5c2h5+h=c6h5c2h3+h2+h 8.00E+13 0.0 8235.0 ! Emdee 1992 c6h5c2h3+oh=c6h4c2h3+h2o 1.63E+08 1.42 1454.0 ! Marinov 1996 c6h5c2h3+h=c6h4c2h3+h2 3.03E+02 3.3 5690.0 ! Marinov 1996 c6h5c2h3+oh=c6h5cch2+h2o 1.00E+07 2.0 2000.0 ! Marinov 1996 c6h5c2h3+h=c6h5cch2+h2 2.00E+07 2.0 6000.0 ! Marinov 1996 c6h5chch+h=c6h5cch2+h 1.00E+14 0.0 0.0 ! Marinov 1996 c6h5cch2+oh=c6h5c2h+h2o 2.00E+13 0.0 0.0 ! Marinov 1996 c6h5cch2+h=c6h5c2h+h2 5.00E+13 0.0 0.0 ! Marinov 1996 c6h5c2h+o=c6h5cco+h 4.80E+09 1.0 0.0 ! (bbb) c6h5cco+o2=c6h5co+co2 1.00E+12 0.0 0.0 ! (ccc) c6h5c2h+oh=c6h4c2h+h2o 1.63E+08 1.42 1454.0 ! Marinov 1996 c6h5c2h+h=c6h4c2h+h2 3.03E+02 3.3 5690.0 ! Marinov 1996 c6h5c2h+ch3=c6h4c2h+ch4 1.67E+12 0.0 15057.0 ! Marinov 1996 c6h4c2h+c2h2=c10h7 1.068E+04 2.324 -657.3 !Total Wang 94 c6h4c2h3+ch3=indene+h+h 2.00E+13 0.0 0.0 ! (eee) ch3c6h4ch3+oh=ch3c6h4ch2+h2o 2.95E+13 0.0 2623.0 ! Marinov 1996 ch3c6h4ch3+o=ch3c6h4ch2+oh 5.00E+08 1.5 8000.0 ! Marinov 1996 ch3c6h4ch3+h=ch3c6h4ch2+h2 3.98E+02 3.44 3120.0 ! Marinov 1996 ch3c6h4ch2+c2h2=c10h10+h 3.20E+11 0.0 7000.0 ! Marinov 1996 ch3c6h4ch2+c2h2=ch3indene+h 3.20E+11 0.0 7000.0 ! Marinov 1996 ch3c6h4ch2+h=ch3c6h4ch3 7.46E+13 0.0 78.0 ! Brand 1990 ch3c6h4ch2+ch3=ch3c6h4c2h5 6.00E+12 0.0 221.0 ! Marinov 1996 indene+oh=indenyl+h2o 3.43E+09 1.18 -447.0 ! Marinov 1996 indene+o=indenyl+oh 1.81E+13 0.0 3080.0 ! Marinov 1996 indene+h=indenyl+h2 2.19E+08 1.77 3000.0 ! Marinov 1996 indenyl+h=indene 2.00E+14 0.0 0.0 ! Marinov 1996 indenyl+o=c6h5chch+co 1.00E+14 0.0 0.0 ! Marinov 1996 indenyl+ho2=c6h5chch+co+oh 1.00E+13 0.0 0.0 ! Marinov 1996 indenyl+c-c5h5=phnthrn+h+h 1.00E+13 0.0 8000.0 ! Marinov 1998 ch3c6h4c2h5+oh=ch3c6h4c2h3+h2o+h 8.43E+12 0.0 2583.0 ! Marinov 1996 ch3c6h4c2h5+h=ch3c6h4c2h3+h2+h 8.00E+13 0.0 8235.0 ! Marinov 1996 ch3c6h4c2h3+oh=indene+h+h2o 1.26E+13 0.0 2583.0 ! Marinov 1996 ch3c6h4c2h3+h=indene+h+h2 3.98E+02 3.44 3120.0 ! Marinov 1996 ch3indene+oh=ch3indenyl+h2o 3.43E+09 1.18 -447.0 ! Marinov 1996 ch3indene+o=ch3indenyl+oh 1.81E+13 0.0 3080.0 ! Marinov 1996 ch3indene+h=ch3indenyl+h2 2.19E+08 1.77 3000.0 ! Marinov 1996 ch3indene+h=indene+ch3 1.20E+13 0.0 5200.0 ! Marinov 1996 ch3indenyl+h=ch3indene 2.00E+14 0.0 0.0 ! Marinov 1996 ch3indenyl+c-c5h5=ch3phnthrn+h+h 1.00E+13 0.0 8000.0 ! Marinov 1998 c10h10+oh=c10h9+h2o 5.00E+06 2.0 0.0 ! Marinov 1996 c10h10+o=c10h9+oh 7.00E+11 0.7 6000.0 ! Marinov 1996 c10h10+h=c10h9+h2 2.00E+05 2.5 2500.0 ! Marinov 1996 c10h9+h=c10h10 1.00E+14 0.0 0.0 ! Marinov 1996 c10h8+h=c10h9 5.00E+14 0.0 5000.0 ! Sauer 1970 c10h8+oh=c10h7+h2o 2.44E+08 1.42 1454.0 ! Marinov 1996 c10h8+oh=c10h7oh+h 9.00E+12 0.0 10592.0 ! Marinov 1996 c10h8+o=c10h7o+h 1.40E+13 0.0 1792.0 ! Frerichs 1990 c10h8+h=c10h7+h2 4.55E+02 3.3 5690.0 ! Marinov 1996 c10h7+h=c10h8 1.00E+14 0.0 0.0 ! Marinov 1996 c10h7+o2=c10h7o+o 1.00E+13 0.0 0.0 ! (fff) c10h7+oh=c10h7o+h 5.00E+13 0.0 0.0 ! Marinov 1996 c10h7+ch3=c10h7ch2+h 2.00E+13 0.0 0.0 ! (eee) c10h7+c2h2=acenphthln+h 1.00E+20 -2.08 12000.0 ! Wang 1994 c10h7+c2h2=c10h7cch+h 1.17E-7 5.248 -9482.0 ! Total Wang 1994 c10h7+c6h5=flrnthn+h+h 5.00E+12 0.0 0.0 ! (ggg) c10h7+c6h6=flrnthn+h+h2 4.00E+11 0.0 4000.0 ! (hhh) c10h7o+h=c10h7oh 1.00E+14 0.0 0.0 ! Marinov 1996 c10h7oh+oh=c10h7o+h2o 2.95E+06 2.0 -1312.0 ! Marinov 1996 c10h7oh+h=c10h7o+h2 1.58E+13 0.0 6100.0 ! Marinov 1996 c10h7o=indenyl+co 7.40E+11 0.0 43850.0 ! Marinov 1996 c10h7ch3+oh=c10h7ch2+h2o 1.27E+13 0.0 2583.0 ! Marinov 1996 c10h7ch3+o=c10h7ch2+oh 5.00E+08 1.5 8000.0 ! Marinov 1996 c10h7ch3+h=c10h7ch2+h2 3.98E+02 3.44 3120.0 ! Marinov 1996 c10h7ch3+h=c10h8+ch3 1.20E+13 0.0 5148.0 ! Marinov 1996 c10h7ch2+h=c10h7ch3 1.00E+14 0.0 0.0 ! Marinov 1996 c10h7ch2+o=c10h7+ch2o 1.00E+14 0.0 0.0 ! Marinov 1996 c10h7ch2+ho2=>c10h7+ch2o+oh 1.00E+13 0.0 0.0 ! Marinov 1996 c10h7ch2+c2h2=bz(a)ndene+h 3.20E+11 0.0 7000.0 ! Marinov 1996 c10h7ch2+ch3=c10h7c2h5 1.19E+13 0.0 221.0 ! Marinov 1996 c10h7c2h5+oh=c10h7c2h3+h2o+h 8.44E+12 0.0 2583.0 ! Marinov 1996 c10h7c2h5+h=c10h7c2h3+h2+h 8.00E+13 0.0 8235.0 ! Marinov 1996 c10h7c2h3+oh=c10h7cch2+h2o 1.00E+07 2.0 2000.0 ! Marinov 1996 c10h7c2h3+h=c10h7cch2+h2 2.00E+07 2.0 6000.0 ! Marinov 1996 c10h7cch2+oh=c10h7cch+h2o 2.00E+13 0.0 0.0 ! Marinov 1996 c10h7cch2+h=c10h7cch+h2 5.00E+13 0.0 0.0 ! Marinov 1996 c10h7cch+oh=c10h6cch+h2o 1.63E+08 1.42 1454.0 ! Marinov 1996 c10h7cch+h=c10h6cch+h2 3.03E+02 3.3 5690.0 ! Marinov 1996 c10h7cch+h=acenphthln+h 8.459E+21 -2.614 7062.6 !Total Wang 1994 c10h6cch+c2h2=phnthryl-1 1.068E+04 2.324 -657.3 ! Total Wang 1994 fluorene+oh=fluoryl+h2o 3.43E+09 1.18 -447.0 ! Marinov 1996 fluorene+o=fluoryl+oh 1.81E+13 0.0 3080.0 ! Marinov 1996 fluorene+h=fluoryl+h2 2.19E+08 1.77 3000.0 ! Marinov 1996 fluoryl+h=fluorene 2.00E+14 0.0 0.0 ! Marinov 1996 bz(a)ndnyl+h=bz(a)ndene 2.00E+14 0.0 0.0 ! Marinov 1996 bz(a)ndene+oh=bz(a)ndnyl+h2o 3.43E+09 1.18 -447.0 ! Marinov 1996 bz(a)ndene+o=bz(a)ndnyl+oh 1.81E+13 0.0 3080.0 ! Marinov 1996 bz(a)ndene+h=bz(a)ndnyl+h2 2.19E+08 1.77 3000.0 ! Marinov 1996 bz(a)ndnyl+c-c5h5=bz(a)phnthrn+h+h 1.00E+13 0.0 8000.0 ! nmm 1996 phnthrn+oh=phnthryl-1+h2o 2.17E+08 1.42 1454.0 ! Marinov 1996 phnthrn+oh=phnthryl-9+h2o 5.43E+07 1.42 1454.0 ! Marinov 1996 phnthrn+oh=phnthrol-1+h 9.00E+12 0.0 10592.0 ! Marinov 1996 phnthrn+oh=phnthrol-9+h 9.00E+12 0.0 10592.0 ! Marinov 1996 phnthrn+h=phnthryl-1+h2 4.04E+02 3.3 5690.0 ! Marinov 1996 phnthrn+h=phnthryl-9+h2 1.01E+02 3.3 5690.0 ! Marinov 1996 anthracn=phnthrn 8.00E+12 0.0 65000.0 ! Colket 1994 phnthryl-1+h=phnthrn 8.00E+13 0.0 0.0 ! Marinov 1996 phnthryl-9+h=phnthrn 8.00E+13 0.0 0.0 ! Marinov 1996 phnthryl-1+o2= phnthroxy-1+o 1.00E+13 0.0 0.0 ! (fff) phnthryl-9+o2= phnthroxy-9+o 1.00E+13 0.0 0.0 ! (fff) phnthrol-1+oh=phnthroxy-1+h2o 2.95E+06 2.0 -1310.0 ! Marinov 1996 phnthrol-1+h=phnthroxy-1+h2 1.59E+13 0.0 6100.0 ! Marinov 1996 phnthroxy-1+h=phnthrol-1 1.00E+14 0.0 0.0 ! Marinov 1996 phnthrol-9+oh=phnthroxy-9+h2o 2.95E+06 2.0 -1310.0 ! Marinov 1996 phnthrol-9+h=phnthroxy-9+h2 1.59E+13 0.0 6100.0 ! Marinov 1996 phnthroxy-9+h=phnthrol-9 1.00E+14 0.0 0.0 ! Marinov 1996 phnthroxy-1=bz(a)ndnyl+co 7.40E+11 0.0 43850.0 ! Marinov 1996 phnthroxy-9=fluoryl+co 7.40E+11 0.0 43850.0 ! Marinov 1996 phnthryl-1+c2h2=pyrene+h 3.492E+10 0.557 5658.0 ! Total Wang 1996 phnthryl-1+ch3=hc4-p(def)pthn+h+h 2.00E+13 0.0 0.0 ! (eee) ch3phnthrn+oh=hc4-p(def)pthn+h2o+h 1.27E+13 0.0 2583.0 ! nmm 1996 ch3phnthrn+h=hc4-p(def)pthn+h2+h 3.98E+02 3.44 3120.0 ! nmm 1996 ch3phnthrn+h=phnthrn+ch3 1.20E+13 0.0 5148.0 !Marinov1996 hc4-p(def)pthn+oh=hc4-p(def)pthyl+h2o 3.43E+09 1.18 -447.0 !nmm96 hc4-p(def)pthn+o=hc4-p(def)pthyl+oh 1.81E+13 0.0 3080.0 !nmm96 hc4-p(def)pthn+h=hc4-p(def)pthyl+h2 2.19E+08 1.77 3000.0 !nmm96 hc4-p(def)pthyl+h=hc4-p(def)pthn 2.00E+14 0.0 0.0 !Marinov 1996 bz(a)phnthrn+h=bz(ghi)fln+h2+h 3.03E+02 3.3 5690.0 !Marinov 1996 bz(a)phnthrn+oh=bz(ghi)fln+h2o+h 1.63E+08 1.42 1454.0 !Marinov 1996 h2ccch+ch2=ch2chcch+h 4.00E+13 0.0 0.0 !Miller 1992 c-c5h5+ch3=ch3cy24pd 1.76E+50 -11.0 18600. !Ritter 1990 ch3cy24pd+h=c-c5h6+ch3 1.00E+13 0.0 1300.0 !Ritter 1990 c6h6+h=ch3cy24pd1 2.39E+27 -3.92 29200. !Ritter 1990 cyc6h7=ch3cy24pd1 5.00E+12 0.0 38100. !Ritter 1990 ch3cy24pd1+h=ch3cy24pd 1.00E+14 0.0 0.0 !Marinov 1998 ch3cy24pd1+h=c-c5h5+ch3 1.00E+14 0.0 0.0 !Marinov 1998 cyc6h7=ch3dcy24pd 5.50E+10 0.0 23500. !Ritter 1990 c6h6+h=cyc6h7 4.87E+56 -12.73 26800. !Ritter 1990 ch3dcy24pd+h2=ch3cy24pd+h 4.00E+12 0.0 15000. !Ritter 1990 fulvene=c6h6 9.84E+37 -7.4 76979. !Shandross1996 fulvene+h=c6h6+h 3.00E+12 0.5 2000.0 !Marinov 1998 fulvene+h=fulvenyl+h2 3.03E+2 3.3 5690. !Marinov 1998 fulvene+oh=fulvenyl+h2o 1.63E+8 1.42 1454. !Marinov 1998 fulvenyl+h=c6h5+h 1.00E+14 0.0 0.0 !Marinov 1998 fulvenyl+o2=c-c5h4o+hco 1.00E+12 0.0 0.0 !Marinov 1998 end